辛蔚, 王玉江, 魏世丞, 王博, 梁义, 袁悦, 徐滨士. 热喷涂制备高熵合金涂层的研究现状与展望[J]. 工程科学学报, 2021, 43(2): 170-178. DOI: 10.13374/j.issn2095-9389.2020.10.20.001
引用本文: 辛蔚, 王玉江, 魏世丞, 王博, 梁义, 袁悦, 徐滨士. 热喷涂制备高熵合金涂层的研究现状与展望[J]. 工程科学学报, 2021, 43(2): 170-178. DOI: 10.13374/j.issn2095-9389.2020.10.20.001
XIN Wei, WANG Yu-jiang, WEI Shi-cheng, WANG Bo, LIANG Yi, YUAN Yue, XU Bin-shi. Research progress of the preparation of high entropy alloy coatings by spraying[J]. Chinese Journal of Engineering, 2021, 43(2): 170-178. DOI: 10.13374/j.issn2095-9389.2020.10.20.001
Citation: XIN Wei, WANG Yu-jiang, WEI Shi-cheng, WANG Bo, LIANG Yi, YUAN Yue, XU Bin-shi. Research progress of the preparation of high entropy alloy coatings by spraying[J]. Chinese Journal of Engineering, 2021, 43(2): 170-178. DOI: 10.13374/j.issn2095-9389.2020.10.20.001

热喷涂制备高熵合金涂层的研究现状与展望

Research progress of the preparation of high entropy alloy coatings by spraying

  • 摘要: 首先介绍了高熵合金的理论基础。然后从不同的热喷涂工艺出发,综述了等离子喷涂、超音速火焰喷涂、高速电弧喷涂、冷喷涂四种技术在制备高熵合金涂层上的研究发展现状,重点从原料选用、制备工艺优化、性能研究、后处理工艺等方面对以上四种热喷涂技术制备高熵合金涂层的研究进行系统地归纳与总结。最后提出现有制备高熵合金涂层的热喷涂技术较少、热喷涂材料受限、高熵合金设计盲目这三个问题,针对性地提出了在优化已有技术的基础上开发新技术;开发高熵陶瓷、高熵非晶合金、高熵复合材料等新型热喷涂材料;沿用材料基因组理念建立高熵合金数据库这三点热喷涂制备高熵合金涂层在未来的发展趋势。

     

    Abstract: In the 1990s, Ye, a scholar from China, broke the routine with a creative idea of the concept of high entropy alloys (HEAs). Since then, new alloys, which breached the traditional concept of “primary component”, have caught great attention of scientists at home and abroad. Due to their excellent properties such as high hardness, strength, wear resistance, corrosion resistance, thermal resistance, and irradiation resistance, HEAs have been considered as a new generation of thermal spray materials with immense potential for industrial applications. Previous studies show similar or even better properties of HEA coatings compared to those of the HEA block. The preparation of the coatings has become the key point since then. Spraying is one of the common methods on preparing HEA coatings, including conventional methods such as plasma spraying, supersonic flame spraying, high-velocity arc spraying, and cold spraying. With their own advantages and disadvantages, appropriate spraying methods and parameters should be selected according to different matrix and spraying materials, which will be discussed in this paper. First, the theoretical basis of the HEAs were introduced. Next, starting from different thermal spraying processes, the research and development status of plasma spraying, supersonic flame spraying, high-velocity arc spraying, and cold spraying on the preparation of HEA coatings were reviewed. Raw material selection, preparation process optimization, performance research, coating post-treatment, and other aspects of the above four thermal spraying techniques to prepare HEA coatings were systematically summarized. Finally, the three problems of limited existing thermal spraying techniques for preparing HEA coatings, limited thermal spraying materials, and aimless design of HEA coatings were proposed. Moreover, three future development issues of new thermal spraying techniques and optimization of existing techniques were discussed along with the development of high entropy ceramics, high entropy amorphous alloys, high entropy composite materials, and other new thermal spray materials. Finally, an HEA database was established to prepare HEA coatings using the concept of material genome to solve the three problems.

     

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