乔芝郁, 邢献然, 郑朝贵, 段淑贞. RECl3-SrCl2-LiCl三元系相图计算[J]. 工程科学学报, 1992, 14(6): 599-606. DOI: 10.13374/j.issn1001-053x.1992.06.002
引用本文: 乔芝郁, 邢献然, 郑朝贵, 段淑贞. RECl3-SrCl2-LiCl三元系相图计算[J]. 工程科学学报, 1992, 14(6): 599-606. DOI: 10.13374/j.issn1001-053x.1992.06.002
Qiao Zhiyu, Xing Xianran, Zheng Chaogui, Duan Shuzhen. Calculation of the RECl3-SrCl2-LiCl Ternary Phase Diagram Systems[J]. Chinese Journal of Engineering, 1992, 14(6): 599-606. DOI: 10.13374/j.issn1001-053x.1992.06.002
Citation: Qiao Zhiyu, Xing Xianran, Zheng Chaogui, Duan Shuzhen. Calculation of the RECl3-SrCl2-LiCl Ternary Phase Diagram Systems[J]. Chinese Journal of Engineering, 1992, 14(6): 599-606. DOI: 10.13374/j.issn1001-053x.1992.06.002

RECl3-SrCl2-LiCl三元系相图计算

Calculation of the RECl3-SrCl2-LiCl Ternary Phase Diagram Systems

  • 摘要: 基于对9个侧边二元系RECl3-SrCl2、RECl3-LiCl、SrCl2-LiCl(其中RE:La、Ce、Pr、Nd)热力学数据和实验相图信息的优化、评估,以及三元系相关热力学性质的分析,计算并讨论了RECl3-SrCl2-LiCl系列4个三元系相图。

     

    Abstract: Based on the optimization and assesment of nine sub-binary phase diagrams and their thermodynamic data:RECl3-SrCl2, RECl3-LiCl, SrCl2-LiCl (RE:La,Ce,Pr,Nd),the relevant ternary thermodynamic properties of RECl3-SrCl2-LiCl systems are predicted and criticized. Using Toop approximation, four ternary phase diagams of the RECl3-SrCl2-LiCl systems are calculated. Their results are briefly discussed.

     

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