Li Xingkang, Li Wenchao, Wang Jian, Zhou Guozhi. The Regulations of Intermediate Compounds Gibbs Free Energies Varying with the Molar Fractions of Components in Equilibrium Phase Diagrams[J]. Chinese Journal of Engineering, 1991, 13(4): 358-366. DOI: 10.13374/j.issn1001-053x.1991.04.030
Citation: Li Xingkang, Li Wenchao, Wang Jian, Zhou Guozhi. The Regulations of Intermediate Compounds Gibbs Free Energies Varying with the Molar Fractions of Components in Equilibrium Phase Diagrams[J]. Chinese Journal of Engineering, 1991, 13(4): 358-366. DOI: 10.13374/j.issn1001-053x.1991.04.030

The Regulations of Intermediate Compounds Gibbs Free Energies Varying with the Molar Fractions of Components in Equilibrium Phase Diagrams

  • A general relationship among the Gibbs free energies of intermediate compounds has been theoretically derived for n (≥2) -component systems. Accordingly it has been reached that the Gibbs free energies of intermediate compounds vary with the molar fractions of components in a certain regulation. In a binary system, the regulation is a quosi-parabola. In a ternary system, it is a quosi-paraboloid, and in n (≥4) -component systems, generally their regulations can not be geometrically descriced.
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