谭启贵, 田键, 田瑞超, 彭浩平. 二氧化碳在裂缝性咸水层内溶解-扩散特性研究[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2024.08.13.002
引用本文: 谭启贵, 田键, 田瑞超, 彭浩平. 二氧化碳在裂缝性咸水层内溶解-扩散特性研究[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2024.08.13.002
Research on dissolution-diffusion characteristics of carbon dioxide in fractured saline aquifers[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2024.08.13.002
Citation: Research on dissolution-diffusion characteristics of carbon dioxide in fractured saline aquifers[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2024.08.13.002

二氧化碳在裂缝性咸水层内溶解-扩散特性研究

Research on dissolution-diffusion characteristics of carbon dioxide in fractured saline aquifers

  • 摘要: 裂缝作为咸水层CO2封存过程CO2主要的快速扩散与逃逸通道,亟待进一步深化认识裂缝对CO2运移或封存影响。本文分析了裂缝性咸水层CO2溶解过程对流-扩散特征,揭示了裂缝宽度、倾角与组合特征对CO2扩散的作用机制,进一步探究了具有离散裂缝网络的较大尺度咸水层内CO2扩散与迁移行为。结果表明:(1)裂缝对咸水层CO2溶解扩散的影响存在时间尺度的双重作用,较短时间内可增强盐水回流上升作用,抑制CO2扩散,而长时间内则可作为CO2快速扩散通道,促进CO2溶解封存;(2)咸水层CO2溶解扩散过程可划分为CO2快速扩散、相对稳定扩散与减速扩散三个阶段,相对稳定扩散阶段的CO2溶解波动性与不同宽度裂缝引起的回流强度密切相关,裂缝倾角与组合特征影响CO2扩散路径与盐水回流发生位置及强度;(3)对于较大尺度的裂缝性咸水层,高度发育的相交裂缝作为CO2优势扩散路径,可增强裂缝欠发育区域或孤立缝区域的回流作用,也可加快CO2扩散至咸水层深部,增强CO2溶解封存。本文研究有助于提高裂缝性咸水层中CO2运移-封存机制的认识,也可为评估裂缝性咸水层CO2封存安全性提供有力借鉴。

     

    Abstract: As the dominant channels of CO2 rapid diffusion and escape in the process of CO2 sequestration in saline aquifers, it is urgent to deeply understand the effect of fractures on CO2 transport and sequestration. In this paper, a coupling simulation model for CO2 convective-diffusion transport in fractured saline aquifers was advanced, which was implemented on the platform of COMSOL Multiphysics 6.0. Through the numerical simulation, the characteristics of CO2 convection-diffusion in fractured saline aquifers were analyzed, the mechanisms of the fracture width, inclination angle and combination characteristics on CO2 diffusion were revealed, and the behavior of CO2 diffusion and migration in large-scale fractured saline aquifers with discrete fracture network was further investigated. The results show that fractures play a time-dependent dual effect on the dissolution and diffusion of CO2 in saline aquifers, which increases with the increment of fracture width. In a short time, the fracture can enhance the rise of brine backflow to inhibit the diffusion of CO2, and disturb the uniform development of CO2 fingerings, resulting in the decline of CO2 concentration; while in a long time, it can act as a preferential channel for CO2 diffusion to promote the dissolution and storage of CO2. The process of CO2 dissolution and diffusion can be divided into three stages: CO2 rapid diffusion, relatively-stable diffusion and slow diffusion. The fluctuation of CO2 dissolution in the relatively-stable diffusion stage is closely related to the backflow intensity caused by fractures with varying width. The fracture inclination angle and combination characteristics can affect the CO2 diffusion path and the location and intensity of saline backflow. Under the condition of a single fracture, dissolved CO2 diffuses inward through both ends of the low-angle fracture, and reflux occurs in the middle of the fracture. For high-angle fractures, dissolved CO2 diffuses upward through the lower oblique end of the fracture, and reflux occurs more concentrated at the upper oblique end of the fracture, which is stronger than that of the low-angle fracture. Under the combined fracture condition, the backflow caused by horizontal parallel fractures is similar to that caused by low angle fractures, and the backflow caused by intersecting fractures is mainly concentrated in the smaller area above the intersecting fractures, while the inclined parallel fractures help to alleviate the backflow effect at the upper end of high-angle fractures. For large-scale fractured saline aquifers, highly developed intersecting fractures, as the dominant channel of CO2 diffusion, can enhance the backflow effect in under-developed fracture areas or isolated fracture areas, inhibiting the development of CO2 fine fingerings and reducing the number of fingerings. They also can accelerate the diffusion of CO2 to the depth area of the saline aquifers to enhance the dissolution and storage of CO2. This work will improve the understanding of CO2 transport-sequestration mechanism in fractured saline aquifers, and can also provide a valuable guidance for evaluating the safety of CO2 sequestration in fractured saline aquifers.

     

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