水系锌离子电池电解液添加剂的研究进展

Research progress on electrolyte additives for aqueous zinc-ion batteries

  • 摘要: 全球清洁能源面临巨大挑战,水系锌离子电池(AZIBs)因锌资源丰富、成本低、安全性高及环境友好等特性,逐渐引起研究学者的广泛关注,也成为锂离子电池的重要替代技术。本文在梳理AZIBs的结构组成、工作原理与发展历程的基础上,指出了其目前面临的问题与挑战,主要包括正极材料容量低、负极循环稳定性差与副反应严重、电解液窗口窄等问题。在当前提升 AZIBs 性能的策略中,复合电解液的制备因操作简便、成本可控、实用性强等优势备受关注。本文深入分析了AZIBs电解液添加剂的研究动态,系统梳理了三种不同类型电解液添加剂的研究进展,明确提出了AZIBs电解液添加剂未来的发展方向。本文的研究工作有助于AZIBs复合电解液的创新发展,有望进一步提升AZIBs的性能,对于新一代储能技术的研发具有积极影响。

     

    Abstract: The global clean energy landscape faces significant challenges. Aqueous zinc-ion batteries (AZIBs) have attracted widespread attention due to the abundant zinc resources, low cost, high safety, and environmentally friendly properties, becoming a promising alternative to lithium-ion batteries. Based on a review of the structural composition, operating principles, and development history of AZIBs, this paper points out the current problems and challenges they face, mainly, including low cathode material capacity, poor anode cycling stability and severe side reactions, and a narrow electrolyte window, etc. Among current strategies for improving AZIB performance, the preparation of composite electrolytes has attracted considerable attention due to their ease of operation, manageable cost and practicality. This paper provides an in-depth analysis of the research trends in AZIBs electrolyte additives, systematically reviewing the progress of three different types of electrolyte additives, and clearly proposing future development directions for AZIBs electrolyte additives. This research contributes to the innovative development of AZIB composite electrolytes, potentially further improving AZIB performance and positively impacting the development of next-generation energy storage technologies.

     

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