高成凤, 王保成, 王树岗, 李建华, 许永霞. 磁场作用下煤系针状焦的制备与电化学性能[J]. 工程科学学报, 2013, 35(1): 91-96. DOI: 10.13374/j.issn1001-053x.2013.01.003
引用本文: 高成凤, 王保成, 王树岗, 李建华, 许永霞. 磁场作用下煤系针状焦的制备与电化学性能[J]. 工程科学学报, 2013, 35(1): 91-96. DOI: 10.13374/j.issn1001-053x.2013.01.003
GAO Cheng-feng, WANG Bao-cheng, WANG Shu-gang, LI Jian-hua, XU Yong-xia. Preparation of coal-based needle coke under magnetic fields and its electrochemical properties[J]. Chinese Journal of Engineering, 2013, 35(1): 91-96. DOI: 10.13374/j.issn1001-053x.2013.01.003
Citation: GAO Cheng-feng, WANG Bao-cheng, WANG Shu-gang, LI Jian-hua, XU Yong-xia. Preparation of coal-based needle coke under magnetic fields and its electrochemical properties[J]. Chinese Journal of Engineering, 2013, 35(1): 91-96. DOI: 10.13374/j.issn1001-053x.2013.01.003

磁场作用下煤系针状焦的制备与电化学性能

Preparation of coal-based needle coke under magnetic fields and its electrochemical properties

  • 摘要: 以除去喹啉不溶物的煤沥青为原料,在自制的载磁反应釜中制备针状焦.通过改变体系聚合反应最大压力及最高温度,对针状焦制备过程中施加磁场后中间相形成阶段的温度、体系最大压力等工艺条件进行了探讨,研究了不同条件下制备的针状焦的结构与电化学性能.采用扫描电子显微镜、X射线衍射仪表征产物的结构特点;采用循环伏安法及电化学阻抗等分析方法表征了不同条件下制备的针状焦的电化学性能.在磁场作用下,体系最大压力为0.4 MPa、体系最高聚合温度为520℃时制备的针状焦具有最佳的结构及电化学性能.

     

    Abstract: Medium temperature coal tar pitch with quinoline insoluble compounds removed was used as the raw material. Coal-based needle coke was prepared in a home-made reactor with a magnetic field. The temperature and the maximum pressure for the formation of the mesophase under the magnetic field were discussed during the preparation of the needle coke. The structure and electrochemical properties of the needle coke prepared under different conditions were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). Under the action of the magnetic field, when the maximum pressure is 0.4 MPa and the maximum temperature is 520℃, the needle coke has the best structure and electrochemical properties.

     

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