彭超豪, 杨穆, 栾奕, 金召奎, 谭僖. 介孔SBA-15/SiO2气凝胶硅-硅复合材料的制备和性能[J]. 工程科学学报, 2016, 38(2): 270-275. DOI: 10.13374/j.issn2095-9389.2016.02.017
引用本文: 彭超豪, 杨穆, 栾奕, 金召奎, 谭僖. 介孔SBA-15/SiO2气凝胶硅-硅复合材料的制备和性能[J]. 工程科学学报, 2016, 38(2): 270-275. DOI: 10.13374/j.issn2095-9389.2016.02.017
PENG Chao-hao, YANG Mu, LUAN Yi, JIN Zhao-kui, TAN Xi. Preparation and properties of a mesoporous SBA-15/silica composited aerogel[J]. Chinese Journal of Engineering, 2016, 38(2): 270-275. DOI: 10.13374/j.issn2095-9389.2016.02.017
Citation: PENG Chao-hao, YANG Mu, LUAN Yi, JIN Zhao-kui, TAN Xi. Preparation and properties of a mesoporous SBA-15/silica composited aerogel[J]. Chinese Journal of Engineering, 2016, 38(2): 270-275. DOI: 10.13374/j.issn2095-9389.2016.02.017

介孔SBA-15/SiO2气凝胶硅-硅复合材料的制备和性能

Preparation and properties of a mesoporous SBA-15/silica composited aerogel

  • 摘要: 以有序介孔二氧化硅颗粒SBA-15为添加剂,利用酸碱两步法制备SBA-15/SiO2气凝胶硅-硅复合材料.研究SBA-15添加量对气凝胶复合材料的形成过程和性能的影响,采用扫描电镜和氮气吸附-脱附对样品的结构进行表征,并测试其力学性能和热导率.结果表明:少量有序介孔二氧化硅材料SBA-15的加入能大大缩短二氧化硅气凝胶形成时间,提高气凝胶复合材料的力学性能,并保持较低的热导率,而材料的比表面积仅略有下降.

     

    Abstract: A mesoporous SBA-15/silica composited aerogel was prepared by a two-step acid-alkali method with SBA-15 as an additive. The effects of the amount of SBA-15 on the formation process and the performance of the eomposited aerogel were investigated. The microstructure of the composited aerogel was characterized by scanning electron microscopy and N2 adsorption-desorption isotherms, and the mechanical properties and thermal conductivity were tested. It is found that as a small amount of SBA-15 is added, the gelation time of silica greatly shortens, the mechanical properties improves, the thernlal conductivity still keeps small, while the specific surface area slightly decreases.

     

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