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碳/氧化锌纳米线阵列/泡沫石墨烯电化学检测叶酸

王宝 林轩宇 黄硕 高鑫 姚龙辉 岳红彦

王宝, 林轩宇, 黄硕, 高鑫, 姚龙辉, 岳红彦. 碳/氧化锌纳米线阵列/泡沫石墨烯电化学检测叶酸[J]. 工程科学学报, 2017, 39(11): 1647-1652. doi: 10.13374/j.issn2095-9389.2017.11.006
引用本文: 王宝, 林轩宇, 黄硕, 高鑫, 姚龙辉, 岳红彦. 碳/氧化锌纳米线阵列/泡沫石墨烯电化学检测叶酸[J]. 工程科学学报, 2017, 39(11): 1647-1652. doi: 10.13374/j.issn2095-9389.2017.11.006
WANG Bao, LIN Xuan-yu, HUANG Shuo, GAO Xin, YAO Long-hui, YUE Hong-yan. Electrochemical determination of folic acid using carbon/ZnO nanowire arrays/graphene foam[J]. Chinese Journal of Engineering, 2017, 39(11): 1647-1652. doi: 10.13374/j.issn2095-9389.2017.11.006
Citation: WANG Bao, LIN Xuan-yu, HUANG Shuo, GAO Xin, YAO Long-hui, YUE Hong-yan. Electrochemical determination of folic acid using carbon/ZnO nanowire arrays/graphene foam[J]. Chinese Journal of Engineering, 2017, 39(11): 1647-1652. doi: 10.13374/j.issn2095-9389.2017.11.006

碳/氧化锌纳米线阵列/泡沫石墨烯电化学检测叶酸

doi: 10.13374/j.issn2095-9389.2017.11.006
基金项目: 

哈尔滨理工大学青年拔尖创新人才培养计划资助项目(201604)

黑龙江博士后科研启动基金资助项目(LBH-Q14117)

哈尔滨市应用技术研究与开发资助项目(2016RAQXJ185)

国家留学人员科技活动资助项目(2015192)

黑龙江省自然科学基金资助项目(LC2015020)

详细信息
  • 中图分类号: TB332;TP212.3

Electrochemical determination of folic acid using carbon/ZnO nanowire arrays/graphene foam

  • 摘要: 通过化学气相沉积法制备三维(3D)泡沫石墨烯(GF),然后利用水热合成法在泡沫石墨烯表面生长氧化锌纳米线阵列(ZnO NWAs),再利用化学气相沉积法在其表面沉积碳(C),得到碳/氧化锌纳米线阵列/泡沫石墨烯(C/ZnO NWAs/GF)复合材料.用该复合材料做电极,采用电化学方法检测叶酸(FA).结果表明,三维泡沫石墨烯具有和模板泡沫镍一样的三维孔状结构,ZnO NWAs均匀且垂直地生长在泡沫石墨烯表面,碳沉积在ZnO NWAs表面.在线性范围为0~60 μmol·L-1内,C/ZnO NWAs/GF电极检测FA时,灵敏度为0.13 μA·μmol-1·L,且在尿酸(UA)干扰下检测FA具有良好的选择性.C/ZnONWAs/GF电极有良好的稳定性和重复性.
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  • 收稿日期:  2017-03-07

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