高碱度烧结矿矿相结构分布模式及形成机理

Distribution patterns and formation mechanisms of the mineralogical structure of high basicity sinter

  • 摘要: 基于烧结矿的非均性, 发现了矿相结构的三种分布模式, 并对矿相结构的形成机理进行了阐述.首先, 基于烧结矿的手标本鉴定特征把某钢厂烧结矿划分成了三类.其次, 对矿相结构的鉴定发现, 第1类、第2类、第3类这三类烧结矿的矿相结构在空间上依次具有"均一状、同心环状、互嵌状"三种分布模式.均一状分布的矿相结构形成于温度较高、还原性较强和混料均匀的稳定条件之中, 主要为交织熔蚀-熔蚀结构, 具有良好的冶金性能; 同心环状分布的矿相结构从外部带到内部带依次为交织熔蚀结构、熔蚀结构和赤铁矿粒状结构, 多以独立单元的形式出现, 其所在区域工艺条件的恶化并不会对烧结矿总体的结构和冶金性能造成太大影响; 交织熔蚀结构、赤铁矿粒状结构和铁酸钙聚集区交叉形成的互嵌状矿相结构, 多形成于温度较低、气流不稳定和混料不均匀的条件之中, 易成片出现而导致烧结矿结构和冶金性能的恶化.最后, 冶金性能分析显示, 第1、2类烧结矿各项冶金性能指标良好, 具有互嵌状分布模式的第3类烧结矿由于矿相结构的不均匀, 冶金性能相对较差.结果表明, 这种基于矿相结构分布模式的研究方式, 有利于对矿相结构形成机理的阐述, 更助于对烧结原料、烧结气氛等工艺条件的调控, 对烧结矿冶金性能的改善具有一定理论价值.

     

    Abstract: Based on their inhomogeneity, three distribution pattern categories of the mineralogical structure of sinters, and their formation mechanisms, were detailed. First, based on the identifiable characteristics of hand specimens, the sinters in a steel plant were divided into three categories (Category 1, Category 2, Category 3). Second, according to the identification characteristics of the microstructure of sinters, three distribution patterns of the mineralogical structure for the three categories of sinters were established, those being uniform, concentric annular, and intercalated. The homogeneous mineral phase structures, which have good metallurgical properties, are mostly interlaced erosion and erosion structure, and the mineral phase structures are formed under stable conditions with higher temperature, stronger reduction, and uniform mixture. The concentric annular mineralogical structures from the outside to the inner belt are interlaced erosion structure, erosion structure, and hematite granular structure, separately. These structures formed under deteriorative process conditions and have no obvious adverse effect on the overall structure and metallurgical properties of sinters. The intercalated mineral phase structure, formed by the interlaced erosion structure, hematite granular structure, and calcium ferrate accumulation area, is mostly formed under conditions of lower temperature, unstable air flow, and inhomogeneous mixture. Getting together may lead to the deterioration of the structure and metallurgical properties of the sinter. Finally, the results of a metallurgical performance analysis show that the metallurgical index of Category 1 and Category 2 are satisfactory, and Category 3, with its intercalated distribution pattern, shows relatively poor metallurgical performance due to the inhomogeneous structure. The above results indicate that the research method based on the distribution pattern of mineral phase structure can be conducive to the discovery of the formation mechanism of the mineralogical structure, and can help to control the sintering raw materials and sintering atmosphere. It has certain theoretical value for improving the metallurgical properties of sinter.

     

/

返回文章
返回