徐艺, 李晨, 任祥, 张熊, 王凯, 孙现众, 马衍伟. 低温锂离子电容器研究进展[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2023.09.20.001
引用本文: 徐艺, 李晨, 任祥, 张熊, 王凯, 孙现众, 马衍伟. 低温锂离子电容器研究进展[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2023.09.20.001
Research progress in low-temperature lithium-ion capacitors[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2023.09.20.001
Citation: Research progress in low-temperature lithium-ion capacitors[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2023.09.20.001

低温锂离子电容器研究进展

Research progress in low-temperature lithium-ion capacitors

  • 摘要: 锂离子电容器(LIC)由双电层电容器(EDLC)正极和锂离子电池(LIB)负极组成,因而兼具了高能量密度、高功率密度和长循环寿命的优势。近年来LIC发展迅速,已逐步实现商业化生产。但LIC同时也继承了锂离子电池较差的低温性能,在低温环境下电解液会变得粘稠甚至凝固,严重影响了离子的正常运输和电荷转移,导致LIC无法在低温条件下正常运转,限制了其全天候、宽温域的应用。因此改善LIC的低温性能成为现阶段亟待解决的问题,受到了业界的广泛关注。众多研究表明电极材料和电解液之间的相互作用直接决定LIC低温电荷存储的过程,是改善LIC低温性能的关键环节。本文从电极材料和电解液两个方面综述了国内外LIC低温性能的研究进展,并对下一代低温LIC进行了展望。

     

    Abstract: Lithium-ion capacitors (LICs) utilize cathode materials of electrical double-layer capacitors and anode materials of lithium-ion batteries, which could combine their advantages of high energy density, high power density, and long cycle life. In recent years, LIC has developed rapidly and has been applied in many fields, such as power storage and new energy transportation. However, while possessing these advantages, it also inherits the poor low-temperature performance of lithium-ion batteries, severely limiting its widespread application. In some occasions, the viscosity of electrolyte may increase or even solidify, affecting the normal transportation and charge transfer of ions. increase in impedance prevents the normal operation of the LIC, severely limiting its all-weather applications. Improving the low-temperature performance of LIC has become an urgent issue, has received widespread attention from all walks of life. Electrodes and electrolytes are the main components of LIC, numerous studies have shown that the relationship between electrode and electrolyte directly determines the energy storage process of LIC at low temperature. Therefore, this article reviews the recent research progresses on the design and fabrication of low-temperature LIC from the viewpoint of electrode and electrolyte, Firstly, the research on key electrode materials for high-performance low-temperature LIC is discussed, including chemical modification, surface modification, ion insertion, and the development of new electrode materials for rapid intercalation of traditional carbon-based materials. Secondly, the electrolyte system that matches the electrode material is also critically reviewed. Starting from the main components of the electrolyte - lithium salts, solvents, and additives - this article summarizes the past year's progress on low-temperature electrolytes in LICs. Emphasis was placed on additives for LIC electrolyte, which, as the essence of the entire electrolyte system, are the most controllable factor in the entire electrolyte system and currently the most available factor for selection. They can reduce the viscosity of the electrolyte with minimal content and improve the low-temperature charging and discharging ability of LIC. Commonly used low-temperature additives such as FEC, VC, PS, LiODFB all demonstrate excellent low-temperature performance. The article concludes by summarizing the research progress of the new generation of low-temperature electrolytes, and provides a tentative outlook toward next-generation LICs with a wide temperature range.

     

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