王肖肖, 黄青松. 低碳钢中高密度超细纳米第二相粒子的快速获取[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2024.01.11.002
引用本文: 王肖肖, 黄青松. 低碳钢中高密度超细纳米第二相粒子的快速获取[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2024.01.11.002
Acquiring high density of ultrafine second phase nanoparticles quickly in low carbon steel[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2024.01.11.002
Citation: Acquiring high density of ultrafine second phase nanoparticles quickly in low carbon steel[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2024.01.11.002

低碳钢中高密度超细纳米第二相粒子的快速获取

Acquiring high density of ultrafine second phase nanoparticles quickly in low carbon steel

  • 摘要: 一般熔炼过程中,非金属化合物以夹杂物的形式存在,对钢的力学性能和寿命都会有损害。不过当夹杂物尺寸小到纳米量级,从而在钢中形成高密度分布的纳米第二相颗粒却能够有效同时提升钢的强度和韧性。本文通过在熔炼过程中施加动态磁场,实现了超短时间内制备Fe-0.04C-1.5Mn-0.5Ti-0.5Al2O3(Fe–TAMO)钢,然后通过轧制和退火处理实现对Fe–TAMO钢中晶粒尺寸优化和等轴化。透射电镜观察发现铸态组织中密集分布着纳米第二相粒子,颗粒的平均直径为2.75±0.803 nm。通过EDS能谱分析,第二相颗粒为Ti-Al-Mn-O的复杂氧化物。利用万能试验机测试了不同状态Fe–TAMO钢的压缩力学性能。该方法极大简化了工艺流程,经过一次快速熔炼即可去除大尺寸的夹杂物,将超细的纳米第二相颗粒均匀分散在整个钢基体中。

     

    Abstract: In the general smelting process, non-metallic compounds exist in the form of inclusions, which will damage the mechanical properties and life of steel. However, when the size of the inclusion is nanometer, the formation of a high-density distribution of second phase nanoparticles in the steel can effectively improve the strength and toughness of the steel. In this paper, Fe-0.04C-1.5Mn-0.5Ti-0.5Al2O3 (Fe–TAMO) steel was prepared in a very short time by applying a dynamic magnetic field in the smelting process, and then the grain size optimization and equiaxed optimization of Fe–TAMO steel were realized by rolling and annealing. The ultrafine second phase particles densely dispersed in the as-cast matrix were observed by transmission electron microscopy, and the average diameter of the particles was 2.75±0.803 nm. According to EDS spectrum analysis, the second phase particles are complex oxides of Ti-Al-Mn-O. The compressive mechanical properties of Fe-TAMO ferrite steel in different states were tested using a universal testing machine. This method greatly simplifies the process, and the large size inclusions can be removed after one quick smelting, and the ultrafine second phase nanoparticles can be uniformly dispersed in the steel matrix.

     

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