黄欣雨, 甘 晨, 张名扬, 邱丽娜, 弓爱君, 董艺. 湿法磷酸萃取技术发展现状与研究进展[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2024.02.19.002
引用本文: 黄欣雨, 甘 晨, 张名扬, 邱丽娜, 弓爱君, 董艺. 湿法磷酸萃取技术发展现状与研究进展[J]. 工程科学学报. DOI: 10.13374/j.issn2095-9389.2024.02.19.002
Development status and research progress of wet phosphoric acid extraction technology[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2024.02.19.002
Citation: Development status and research progress of wet phosphoric acid extraction technology[J]. Chinese Journal of Engineering. DOI: 10.13374/j.issn2095-9389.2024.02.19.002

湿法磷酸萃取技术发展现状与研究进展

Development status and research progress of wet phosphoric acid extraction technology

  • 摘要: 磷酸作为一种重要的化工原料,在化工业中占有极其重要的地位。磷酸的应用主要由磷酸的纯度决定。低纯度磷酸可用于工业和农业领域,而高纯度磷酸则可用于医药、食品和电子等行业。我国磷矿石以低品位磷矿为主,主要用湿法磷酸处理,相比热法磷酸更加清洁环保,但产品杂质含量多种类复杂,故发展磷酸净化技术尤为重要。本文从湿法磷酸纯化技术中的萃取法出发,综述了萃取法的主要研究进展。重点介绍了溶剂萃取法、双水相萃取法、反胶团萃取法、超声协助萃取法和超临界流体萃取法的基本原理和发展趋势。分析了不同萃取方法的优缺点、分离效果和适用条件。突出介绍了溶剂萃取法,梳理了磷酸除杂的主要萃取剂,特别强调了复合萃取剂和新型萃取剂在磷酸纯化方面的显著优势,最后,对磷酸的萃取技术做出了前景展望。

     

    Abstract: As an important chemical raw material, phosphoric acid occupies an extremely important position in the chemical industry. The application of phosphoric acid is mainly determined by the purity of phosphoric acid, low purity phosphoric acid can be used in industrial and agricultural neighborhoods, while high purity phosphoric acid can be used in pharmaceutical, food, electronics and other industries. In recent years, with the increasing demand for batteries and semiconductors, the purity of phosphoric acid has put forward higher requirements. There are two main manufacturing methods of phosphoric acid, among them, thermal phosphoric acid consumes large energy and environmentally unfriendly, which does not meet the needs of China's development of green chemistry. Wet phosphoric acid has low energy consumption and bulk and complex product impurities, which is more suitable for treating low-grade phosphate rock in China. Compared with chemical precipitation, crystallization, electrodialysis, ion exchange resin and other purification technologies, the extraction method has the advantages of green environment, simple operation and large production capacity, and is a phosphoric acid purification method with great development prospects. This article summarizes in detail the research status of various extraction methods in recent years. The basic principles and development trends of solvent extraction, aqueous two-phase extraction, reverse micelles extraction, ultrasonic-assisted extraction and supercritical fluid extraction were emphatically introduced , and the solvent extraction method and various extractants were emphatically sorted out. The research of single extractants such as TBP, MIBK, and NOA mainly focuses on exploring the optimal extraction conditions (O/A phase ratio, temperature, and air pressure), but a single extractant can usually only extract a single impurity and cannot meet the extraction of multiple impurities, so the composite extractant has significant advantages in phosphoric acid purification. At present, researches highlight composite extractants are mainly on the proportion of extractants(usually the volume ratio) and the optimal conditions for extraction. In addition to composite extractants, the new extractants can also solve the problem of low extraction efficiency of a single extractant. Finally, the future development trend of extraction technology of phosphoric acid is proposed: 1) development of green composite extractants, new extractants, new materials combined with extractants that can achieve efficient separation of impurities from phosphoric acid, 2) increase the research on the application of aqueous two-phase extraction and reverse micelles extraction in ion extraction, and explore new aqueous phase systems, 3) use ultrasonic technology to accelerate the extraction process, and study how supercritical fluids can improve the solubility and extraction efficiency of ions. Reduce costs and explore specific application areas.

     

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