Liu Sijun, Li Xingkang, Wang Jian, Li Wenchao. Stability of A Determination of Intermediate Compound Standard Gibbs Free Energy of Formation[J]. Chinese Journal of Engineering, 1992, 14(6): 629-636. DOI: 10.13374/j.issn1001-053x.1992.06.008
Citation: Liu Sijun, Li Xingkang, Wang Jian, Li Wenchao. Stability of A Determination of Intermediate Compound Standard Gibbs Free Energy of Formation[J]. Chinese Journal of Engineering, 1992, 14(6): 629-636. DOI: 10.13374/j.issn1001-053x.1992.06.008

Stability of A Determination of Intermediate Compound Standard Gibbs Free Energy of Formation

  • Based on principles of thermodynamics, it is derived that: in a binary system, a quasi-parabola regulation must be obeyed by the standard Gibbs free energy of formation of compound. Extended to ternary systems, a quasi-paraboloid regulation also is done. The stabilities of intermediate compound in binary systems containing a rare earth element are criticized.
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