Shi Qingrong, Duan Shuzhen, Wu Shimin. Electrochemical Reduction of B(Ⅲ) in Molten Fluorides[J]. Chinese Journal of Engineering, 1994, 16(6): 599-603. DOI: 10.13374/j.issn1001-053x.1994.06.020
Citation:
Shi Qingrong, Duan Shuzhen, Wu Shimin. Electrochemical Reduction of B(Ⅲ) in Molten Fluorides[J]. Chinese Journal of Engineering, 1994, 16(6): 599-603. DOI: 10.13374/j.issn1001-053x.1994.06.020
Shi Qingrong, Duan Shuzhen, Wu Shimin. Electrochemical Reduction of B(Ⅲ) in Molten Fluorides[J]. Chinese Journal of Engineering, 1994, 16(6): 599-603. DOI: 10.13374/j.issn1001-053x.1994.06.020
Citation:
Shi Qingrong, Duan Shuzhen, Wu Shimin. Electrochemical Reduction of B(Ⅲ) in Molten Fluorides[J]. Chinese Journal of Engineering, 1994, 16(6): 599-603. DOI: 10.13374/j.issn1001-053x.1994.06.020
Electrochemical Reduction of B(Ⅲ) in Molten Fluorides
The mechanism of the cathode process of B(Ⅲ) on a platinum electrode in molten LiF-NaF-KBF4 at 750℃ has been investigated by means of cyclic voltammetry and convolution technique.It Was found that the electrochemical reduction of B(Ⅲ) to elementary boron is a simple three-electron process involving alloy formation with the platinum electrode.The cathodic process is very close to a reversible process and is diffusion controlled.
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