Kinetics of Calcium Ferrite Formation at Initial Stage of Reaction in CaO-Fe2O3 Mixed Bed
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Abstract
Kinetical model of calcium ferrite formation at initial stage of reaction in CaO-Fe2O3 mixed bed was obtained by using terms of theory as follows:
1-k1(1-k2BRv)2/3-k2(1+k1BRv)2/3=(2k1Mf/ρfrf2)·DcΔCt.br/>其中k1=(ρf-ρcf)/(ρf-ρc),k2=(ρcf-ρc)/(ρf-ρc),B=1+Mcρfm/Mfρc. The results calculated by this model is identical very well with the experimental data, and the interdif-fusion coefficients of CaO in monocalcium ferrite were determined as 4.34×10-9cm2/s and 2.32×10-8cm2/s respectively at 1160 and 1190℃.
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