ZHAO Hongmei, XU Xiaowei, LIU Zhifu, LI Yuping. Function of Ca3N2 in the Formation of BN[J]. Chinese Journal of Engineering, 2001, 23(3): 234-236. DOI: 10.13374/j.issn1001-053x.2001.03.037
Citation: ZHAO Hongmei, XU Xiaowei, LIU Zhifu, LI Yuping. Function of Ca3N2 in the Formation of BN[J]. Chinese Journal of Engineering, 2001, 23(3): 234-236. DOI: 10.13374/j.issn1001-053x.2001.03.037

Function of Ca3N2 in the Formation of BN

  • The function of Ca3N2 on the reaction between B4C and NH4Cl was investigated.Under normal pressure and high temperature. The results showed that there was small amount of hBN formed in the reaction at 950℃, and little change took place after Ca3N2 was added. The amount of hBN achieved from the reaction at 1200℃ was more than that at 950℃, and much more hBN was gained after adding Ca3N2. It was concluded that Ca3N2 performed catalytic function in the formation of hBN. In addition, the results also indicated that the catalytic function of Ca3N2 was less ho that of Li3N, and they could only act as catalyst at melting state.
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