SUN Xiao-fei, WANG Gui-hua, WANG Wen-shan, WANG De-ren, HE Ye-dong. Effect of the addition of K3AIF6 into electrolytes on the corrosion behavior of NiFe2O4-based cermet anodes[J]. Chinese Journal of Engineering, 2010, 32(12): 1591-1595. DOI: 10.13374/j.issn1001-053x.2010.12.013
Citation: SUN Xiao-fei, WANG Gui-hua, WANG Wen-shan, WANG De-ren, HE Ye-dong. Effect of the addition of K3AIF6 into electrolytes on the corrosion behavior of NiFe2O4-based cermet anodes[J]. Chinese Journal of Engineering, 2010, 32(12): 1591-1595. DOI: 10.13374/j.issn1001-053x.2010.12.013

Effect of the addition of K3AIF6 into electrolytes on the corrosion behavior of NiFe2O4-based cermet anodes

  • 5Cu-9.5NiO-85.5NiFe2O4 cermet anodes were tested in different low-temperature electrolytes for aluminum electrolysis.Post-electrolysis microscopic examination of the anodes was carried out by scanning electron microscopy(SEM) and X-ray diffraction(XRD).The contents of impurities both in the bath and aluminum were measured by inductively coupled plasma atomic emission spectrometry(ICP-AES).The corrosion rates of the anodes in different electrolytes were calculated and compared.The results indicate that when the addition amount of K3AlF6 is around 20% in Na3AlF6-30AlF3-based electrolytes, the anodes show good anti-corrosion properties.
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